When does Pearl enter Valorant's Competitive queue?

Pearl is the latest map in Valorant and will be available in the Competitive queue tomorrow. It went live with Patch 5.0 on June 22, with the launch of the new Episode.

Valorant Episode 5 Dimension, featuring new map Pearl, available for free from June 22 - Onono

Valorant patch notes – latest balance changes and updates

Valorant Is Getting a New Rank Called 'Ascendant' Between Diamond & Immortal; Full 5.0 Patch Notes

UPDATED* Valorant Episode 5 Act 1: Release Date, Patch Notes, New Map & Rank

VALORANT Patch Notes 6.03 : r/ValorantCompetitive

Valorant Act 3 Episode 6 Release Date and Details - Valorant Guide - IGN

Valorant's new map Pearl has a big queue dodging problem

Valorant Update 5.0 Patch Notes

All Valorant Maps That Have Been Released So Far

Valorant Episode 5 - New Map Pearl, Competitive Rank, And More - GameSpot